OXIDATION AND CHEMILUMINESCENCE OF TETRAKIS (DIMETHYLAMINO) ETHYLENE. I. REVERSIBLE REACTIONS OF OXYGEN WITH TETRAKIS (DIMETHYLAMINO) ETHYLENE AND N-DECANE
NAVAL ORDNANCE TEST STATION CHINA LAKE CA
Pagination or Media Count:
The solubility and heat of solution of oxygen in n-decane and tetrakis dimethylamino - ethylene TMAE were measured and found to be almost equal. The spectrally measurable interaction species, TMAE-02 and n-C10H22-02, are shown to have very low enthalpy of formation -1.2 and -0.4 kcal.. Thus, in nonpolar media the good electron donor TMAE and poor electron donor n-decane react similarly with oxygen.
- Organic Chemistry
- Radiation and Nuclear Chemistry