Accession Number:

AD0625455

Title:

THERMODYNAMICS OF THE LIQUID-LIQUID CRITICAL MIXING REGION.

Descriptive Note:

Final rept. 5 Mar 58-31 Dec 63,

Corporate Author:

CALIFORNIA UNIV RIVERSIDE DEPT OF CHEMISTRY

Personal Author(s):

• Schmidt,Hartland H.
• Opdycke,Jack

Report Date:

1965-02-15

Pagination or Media Count:

38.0

Abstract:

An improvement was made upon the apparatus used for heat capacity measurements and the measurements were refined to the extent that they can now reasonably be expected to give data of the high order of precision required for crucial tests of theories. The bulk of the report is devoted to a description of the apparatus developed, the art involved in its operation, and the results obtained on two particular critical systems. An attempt was made to measure the partial vapor pressure and hence the fugacity of components in a liquid-liquid near-critical mixture as a function of composition.

Descriptors:

• *PHASE STUDIES
• THERMODYNAMICS
• STATISTICAL MECHANICS
• CONDENSATION
• LIQUIDS
• MANOMETERS

Subject Categories:

• Thermodynamics

Distribution Statement:

APPROVED FOR PUBLIC RELEASE