Accession Number:

AD0621614

Title:

THE SYNTHESES AND PROPERTIES OF SOME COMPLEXES DERIVED FROM SULPHAMIDE,

Descriptive Note:

Corporate Author:

ILLINOIS UNIV URBANA NOYES CHEMICAL LAB

Personal Author(s):

Report Date:

1965-01-19

Pagination or Media Count:

8.0

Abstract:

By means of reactions involving sulphamide, various amines or ammonia, and certain dipositive metal ions, a number of solid adducts have been isolated. These include compounds of the types MBB SuX2, MBB2 Su X2, and MBB2 Su2X2 where M is commonly Cu, BB is two molecules of ammonia or a diamine such as H2 NC2H4NH2en, H2NCH2CHCH3NH2 1,2-pn, or H2 NC3H6NH21,3-pn, Su is sulphamide, and X is a uninegative ion or half a dinegative ion. Such adducts are stable in the solid state but decompose into the corresponding metal ammine complex and sulphamide in contact with water. The infra-red spectra indicate only weak interactions between sulphamide and the metal ions. N-substituted sulphamides and substituted de-ammonation products of sulphamide are even weaker ligands than sulphamide. Author

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Distribution Statement:

APPROVED FOR PUBLIC RELEASE