Accession Number:

AD0621283

Title:

Studies on the Hydrolysis of Metal Ions. Part 49. An emf Study of Lithium Hydroxide in 3 M (NaClO4) Medium

Descriptive Note:

Journal article

Corporate Author:

TOKYO INST OF TECHNOLOGY (JAPAN)

Personal Author(s):

Report Date:

1963-11-19

Pagination or Media Count:

14.0

Abstract:

An emf study was made in a system of various concentrations of lithium and hydroxide ions in sodium perchlorate medium using a hydrogen electrode at 25 deg C. The general composition of the cell is PtH2, B M Li, 3- B M Na, A M OH-, 3-A M ClO4-Ref where Ref 3 M NaClO4 2.99 M Na, 0.01 M Ag, 3 M ClO4-AgCl,Ag. From the difference in emfs between sodium hydroxide solutions with and without lithium ions, the following formation constant of lithium hydroxide was estimated Li OH- reversibly yields LiOH, K 0.66 0.02 log K -0.18 0.01.

Subject Categories:

  • Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE