Accession Number:

AD0621230

Title:

DERIVATIVES OF SULFENIC ACIDS. XXXII. STUDIES OF THIOPEROXIDES. PART 4. REACTIONS OF TRICHLOROMETHANE SULFENYL CHLORIDE WITH 1,2EPOXIDES AND ALCOHOLS,

Descriptive Note:

Corporate Author:

UNIVERSITY OF SOUTHERN CALIFORNIA LOS ANGELES DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1958-01-01

Pagination or Media Count:

7.0

Abstract:

Trichloromethane sulfenyl chloride I reacts with 1,2epoxides and with meso-butadiene dioxide to form betachloroalkyl trichloromethane sulfenates. The reaction is catalyzed by t-amines and identical products are obtained by substituting appropriate beta-chloro alcohols for the epoxides. The results agree with the mechanism which postulates trans opening of the epoxide rings, as previously suggested for the similar reactions of 2,4-dinitrobenzene sulfenyl chloride. The new products from reaction of I with epoxides and certain alcohols are reported. Author

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Distribution Statement:

APPROVED FOR PUBLIC RELEASE