THE MAGNETIC TRANSITION IN WURSTER'S BLUE PERCHLORATE.
GRONINGEN RIJKSUNIVERSITEIT (NETHERLANDS) LAB OF PHYSICAL CHEMISTRY
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A study was made of the magnetic transition in Wursters Blue Perchlorate. From the spectroscopic and magnetic evidence it follows that the transition is due to a disproportionation of the tetra-methyl-p-phenylenediamine ion TMPD yields TMPD TMPD. Connected with this is a surprisingly high conductivity in the transition range. Author