Accession Number:

AD0617976

Title:

THE INTERACTION OF HYDRAZINE WITH BORON AND ALUMINUM HALIDES,

Descriptive Note:

Corporate Author:

MCGILL UNIV MONTREAL (QUEBEC) INORGANIC CHEMISTRY LAB

Personal Author(s):

Report Date:

1963-02-26

Pagination or Media Count:

6.0

Abstract:

The interaction of boron halides BX3 where X is Cl or Br or aluminum halides Al2X6 where X is Cl, Br, or I with hydrazine is characterized by the elimination of hydrogen halide and the formation of substances with boronor aluminum- nitrogen linkages. The hydrogen halide appears in the products as hydrazine hydrohalide, which can be separated by a hydrazine washing technique, leaving a polymeric material with empirical formula MN4H5 where M is Al or B. A reaction scheme is proposed and possible structures of this polymeric product are discussed. Author

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Distribution Statement:

APPROVED FOR PUBLIC RELEASE