Accession Number:

AD0617870

Title:

PRESENTATION AND POLYMERIZATION OF DITHIOCARBOLIC ACID-S, S'-DIVINYLESTER(DARSTELLUNG UND POLYMERISATION VON DITHIOKOHLENSAURES,S'-DIVINYLESTER),

Descriptive Note:

Corporate Author:

POLYTECHNIC INST OF BROOKLYN N Y DEPT OF CHEMISTRY

Report Date:

1960-11-17

Pagination or Media Count:

6.0

Abstract:

S,S-Divinyldithiocarbonate was prepared by the dehydrohalogenation of the reaction product of 1 mole of phosgene and 2 moles of ethylene sulfide. The divinyl compound was susceptible to radical polymerization. Solution polymerization in benzene yielded a soluble polymer, via an intromolecular-intermolecular reaction mechanism, with the alpha-methylenetrimethylenedithiocarbonate group as main chain unit. Author

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Distribution Statement:

APPROVED FOR PUBLIC RELEASE