Accession Number:

AD0617448

Title:

THE REFINEMENT OF THE CRYSTAL STRUCTURE OF NORBORNADIENE PALLADIUM CHLORIDE.

Descriptive Note:

Revised ed.,

Corporate Author:

IOWA UNIV IOWA CITY DEPT OF CHEMISTRY

Report Date:

1964-08-12

Pagination or Media Count:

3.0

Abstract:

The crystal structure of norbornadiene palladium chloride has been refined with data obtained by counter methods from crystals maintained at liquid nitrogen temperature. After refinement the conventional discrepancy index R0.0275. The carbon-carbon single bond distances in the norbornadiene molecule are normal 1.547, 1.552, 1.554 0.006 A the double bond distances are barely significantly longer than normal 1.366, 1.366 0.010 A. The observed double bond distance is now compatible with the infrared spectrum of the complexed olefin. Author

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE