PHYSICAL AND PREPARATIVE STUDIES OF TRANSITION METAL CHELATES
Interim technical rept. for Dec 1963-Aug 1964
TULANE UNIV NEW ORLEANS LA
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The partial paramagnetism of several nickel 2 unsaturated Beta- ketoamine complexes has been found to be due to decomposition and water effects. Several other ketoamine complexes have been prepared, but none has been found suitable for vapor phase chromatography. A new 8-hydroxyquinolato complex of molybdenum has been isolated and the isomers of trichlorotripyridinemolybdenum 3 have been studied. Investigations of tungsten 3 and -4 complexes are in progress. Calculations of absorption band spectra for several trifluoromethyltetrazolyl complexes have been made and structures determined.
- Organic Chemistry