Accession Number:

AD0614476

Title:

THE OXIDATION OF ARSENIC (III) AND ANTIMONY (III).

Descriptive Note:

Final progress rept. for 1 Feb 63-1 Feb 65,

Corporate Author:

VIRGINIA POLYTECHNIC INST BLACKSBURG

Personal Author(s):

Report Date:

1965-02-01

Pagination or Media Count:

19.0

Abstract:

The kinetics of the CrVI-AsIII reaction have been measured in perchloric acid solutions, acetic acid solutions, acetoc acid-acetate buffers, NH4NO3, and H2PO4 - HPO4 buffers. The reaction shows catalysis by H, and HOAc. The general form of the rate laws is given. In phosphate buffers, a CrVI.H2PO4 complex is indicated as an oxidizing agent.

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE