Accession Number:

AD0612245

Title:

THE THERMAL DECOMPOSITION OF METAL COMPLEXES. XIII. SOME TETRAMMINEPALLADIUM(II) COMPLEXES,

Descriptive Note:

Corporate Author:

TEXAS TECHNOLOGICAL COLL LUBBOCK

Personal Author(s):

• Wendlandt,W. W.
• Funes,L. A.

Report Date:

1964-02-07

Pagination or Media Count:

7.0

Abstract:

The thermal dissociation of the palladiumII tetramminecomplexes, PdNH34X where X is 2Cl, 2Br, 2I, 2NO3, and SO4, was studied by thermogravimetry, DTA, GE, and by analysis of the pyrolysis products. The complexes, except for the nitrate and sulphate, dissociated to give the trans-diammine-complexes, PdNH32X. The diammine-iodide and bromide complexes dissociated to give the corresponding anhydrous metal halides, PddX2. The stoicheiometry for the thermal dissociation of the PdNH32X2 complexes, where X was Cl, Br, and I, was determined. Author

Descriptors:

• (*PYROLYSIS
• COMPLEX COMPOUNDS)
• (*COMPLEX COMPOUNDS
• PYROLYSIS)
• (*PALLADIUM COMPOUNDS
• PYROLYSIS)
• (*AMMONIUM COMPOUNDS
• PYROLYSIS)
• CHLORIDES
• BROMIDES
• IODIDES
• NITRATES
• SULFATES
• THERMOCHEMISTRY
• DISSOCIATION

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE