Accession Number:

AD0611964

Title:

ELECTRON PARAMAGNETIC RESONANCE EXPERIMENTS WITH TI(3+) IONS IN RBA1(SO4)2.12H20,

Descriptive Note:

Corporate Author:

MCGILL UNIV MONTREAL (QUEBEC) EATON ELECTRONICS RESEARCH LAB

Personal Author(s):

Report Date:

1964-05-05

Pagination or Media Count:

10.0

Abstract:

The paramagnetic resonance spectrum of the Ti3 ion in cubic RbAlSO42. 12H2O single crystals was studied in the 100 and 110 planes at 4.2K with an X-band microwave spectrometer. The spectrum, which consists of a maximum of 12 lines, has been explained by considering a model of 12 magnetic complexes which are related to each other through the symmetry elements of the Th 2m3 point group of the Rb alum lattice. For the spin Hamiltonian with S 12 three g factors have been determined--1.895, 1.715, and 1.767--within an accuracy of 0.002, indicating the existence of a crystal electric field of orthorhombic symmetry. Author

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE