Vaporization of Compounds and Alloys at High Temperatures. Part 24. Mass Spectrometric Determination of the Stability of Gaseous Molybdates, Tungstates, Molybdites and Tungstites of Magnesium, Calcium, Strontium, and Tin
Technical documentary rept.
BRUSSELS UNIV (BELGIUM)
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A number of ternary oxides have been identified in the gas phase by mass spectrometry, while vaporizing MgO, CaO, SrO and SnO2 Sn from Mo and W crucibles. The approximate stabilities of the gaseous molecules MgMoO4, CaMoO4, SrMoO4, MgWO4, CaWO4, SrWO4, SrMoO3, CaWO3, CaMoO3, SnWO4 and Sn2WO5 were deduced from the measurements. The dissociation energies kcalmole into gaseous oxides are presented.
- Physical Chemistry