Accession Number:

AD0607616

Title:

NEW HYPOFLUORITES CONTAINING NITROGEN

Descriptive Note:

Annual rept. no. 1

Corporate Author:

IDAHO UNIV MOSCOW

Personal Author(s):

• Shreeve, Jean'ne M.

Report Date:

1964-10-01

Pagination or Media Count:

10.0

Abstract:

Attempts to prepare NF2OF by 1 the fluorination of nitric oxide 2 the reaction of N2F4 HgO and 3 the catalytic fluorination of NF2OSO2F, were unsuccessful. Some preliminary data on the thermal decomposition of NF2OSO2F are included. Catalytic fluorination of trifluoro nitrosomethane yielded CF32NOCF3 which was more completely characterized and very likely CF3F NOCF3 is also produced. As the other member of this series, NF2OCF3 was prepared and partially characterized. CF32NOCF3 is stable to at least 200C even in the presence of equimolar amounts of elemental fluorine. The thermal decomposition of CF3COONO also gives CF32NOCF3 in about 5 yields.

Descriptors:

• *OXIDIZERS
• *OXYFLUORIDES
• AMINES
• CATALYSIS
• CHEMICAL ANALYSIS
• FLUORINATION
• METHANE
• NITRATES
• PYROLYSIS
• STABILITY
• SYNTHESIS(CHEMISTRY)
• ULTRAVIOLET RADIATION

Subject Categories:

• Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE