Accession Number:

AD0606673

Title:

SPECTROSCOPIC STUDIES: PART 4, THE PREDICTION OF CONFORMATION FROM BOND STRETCHING FREQUENCIES.

Descriptive Note:

Scientific rept. no. 10,

Corporate Author:

UNIVERSITY COLL OF WALES ABERYSTWYTH EDWARD DAVIES CHEMICAL LAB

Personal Author(s):

Report Date:

1964-07-07

Pagination or Media Count:

16.0

Abstract:

A study on X.CH2 .CH2 .Y molecules shows that a relation exists between the CX-bond stretching frequency and the electronegativity product CHI X CHI Y when X and Y are in the trans position. This correlation is used to demonstrate that the gauche isomer is the more stable conformer for ClCH2 .CH2 CN and BrCH2.CH2 CN. Author

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE