POLYMERIZATION KINETICS BY MEANS OF DIFFERENTIAL THERMAL ANALYSIS. PART II. DERIVATION OF RATE AND ENTHALPY EQUATIONS
Rept. for Nov 1962-Nov 1963
AIR FORCE MATERIALS LAB WRIGHT-PATTERSON AFB OH
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Rate equations and enthalpic parameters were derived for use in differential thermal analysis DTA of polymerization reactions. General free radical polymerization kinetics are discussed and the existence of a stationary state under DTA conditions was demonstrated, by comparison of a theoretical computer curve, based on stationary state assumption, with actual experimental conditions. These curves appear to be almost superimposable.
- Polymer Chemistry