Accession Number:

AD0605723

Title:

INFLUENCE OF IONIC SOLUTES UPON RELAXATION TIMES,

Descriptive Note:

Corporate Author:

KING'S COLL LONDON (ENGLAND)

Personal Author(s):

Report Date:

1964-07-01

Pagination or Media Count:

64.0

Abstract:

Sin-lattice relaxation times were measured by the direct N.M.R. method for dilute aqueous solutions of NiII in presence of cyanide, halide, acetone, t-butyl alcohol, trimethyl phosphate, edta and trien, for some of these solutes in the absence of paramagnetic ions. Spin-spin relaxation times were used to measure the influence of hydrogen ions on complex formation between water and acetaldehyde or pyruvic acid. Complex formation between methanol and other solvents through hydrogen-bonding was investigated by measurements of chemical shifts, the influence of methoxide ions on multiplet collapse, and indicator measurements. Author

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE