Accession Number:

AD0602990

Title:

RESEARCH ON THE INFLUENCE OF THE NATURE OF THE LIGAND ON THE STEREOCHEMISTRY TRY OF THE NICKEL (II) AND OTHER 1ST ROW TRANSITION METAL COMPLEXES WITH SCHIFF BASES.

Descriptive Note:

Final technical rept. no. 1, 1 Jun 63-1 May 64,

Corporate Author:

FLORENCE UNIV (ITALY)

Personal Author(s):

Report Date:

1964-05-01

Pagination or Media Count:

32.0

Abstract:

The solid and liquid state steric configurations of several bis-N-alkylsalicylaldimino-nickel II complexes were examined spectrophotometrically and by magnetic and dielectric polarization measurements. It was found that the n-propyl derivatives are planar, the t-butyl derivatives pseudo-tetrahedral, and the secalkyl derivatives either planar or pseudo-tetrahedral. Thermochemical, electronic, and steric implications are discussed. R-N-salicylaldimine-cobaltIII complexes were found to exist in the trans-octahedral configuration only.

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE