Accession Number:

AD0602087

Title:

CHEMISTRY OF DECABORANE-PHOSPHORUS COMPOUNDS. V. SYNTHESIS AND PHOSPHINATION OF BROMOCARBORANES.

Descriptive Note:

Technical rept. no. 24

Corporate Author:

OLIN MATHIESON CHEMICAL CORP NEW HAVEN CONN

Report Date:

1964-07-01

Pagination or Media Count:

16.0

Abstract:

Aluminum halide catalyzed bromination of carborane and neocarborane resulted in a stepwise substitution with tri bromocarborane and dibromoneocarborane respectively, as the ultimate products. Further halogenation was achieved with chlorine to give B10H2Br3Cl5C2H2, B10Br2Cl8C2H2, and neo-B10Br2Cl8C2H2. Some reactions of the bromocarboranes including the preparation of phosphorus derivatives are described. Author

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE