Accession Number:

AD0601677

Title:

DEVELOPMENT OF NONFLAMMABLE HYDRAULIC FLUIDS AND LUBRICANTS.

Descriptive Note:

Bimonthly progress rept. no. 4, 18 Apr-17 Jun 64,

Corporate Author:

OLIN MATHIESON CHEMICAL CORP NEW HAVEN CONN

Personal Author(s):

• Kober,E. H.
• Lederle,H. F.
• Ottmann,G. F.

Report Date:

1964-06-24

Pagination or Media Count:

38.0

Abstract:

A number of mixed substituted trimeric and tetrameric arylamino-polyfluoroalkoxy phosphonitriles were prepared. A typical representative of this new class of compounds, bisN-methylanilino-hexakis1,1-di H-trifluoroethoxy phosphonitrile, passed the hydrolytic stability test of specification MIL-H-19457A and gave also excellent results in the Falex wear test. Another representative, bisN-methylanilino- tetrakis 1,1-di H-trifluoroethoxy phosphonitrile, gave viscosities approaching those of the same specification. Catalytic reduction of trimeric bisp-nitrophenyl phosphonitrilate afforded bisp-aminophenyl phosphonitrilate in excellent yield. Ethoxylation of the latter resulted in the consumption of 10.8 moles of ethylene oxide per amino-group to give a water soluble material having potential for use in water base hydraulic fluids. Representatives of the novel class of arylthio-polyfluoroalkoxy phosphonitriles were synthesized but were found to display slow hydrolytic instability and poor lubricity. Author

Descriptors:

• *HYDRAULIC FLUIDS
• *LUBRICANTS
• *ORGANIC NITROGEN COMPOUNDS
• *ORGANIC PHOSPHORUS COMPOUNDS
• FLAMMABILITY
• FLAMMABILITY
• SYNTHESIS(CHEMISTRY)
• STABILITY
• VISCOSITY
• WEAR RESISTANCE
• LUBRICATION
• SOLUBILITY
• WATER
• REDUCTION(CHEMISTRY)

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE