Accession Number:

AD0502016

Title:

Inorganic Halogen Oxidizers.

Descriptive Note:

Annual rept. 30 May 68-31 Mar 69,

Corporate Author:

ROCKETDYNE CANOGA PARK CALIF

Personal Author(s):

• Pilipovich,D.
• Christe,K. O.
• Schanck,C. J.
• Wilson,R. D.

Report Date:

1969-05-31

Pagination or Media Count:

241.0

Abstract:

New species such as ClF5O, ClF3O2, and BrF7 were sought via glow discharge and high-temperaturehigh-pressure fluorinations. These syntheses were unsuccessful with covalent, anionic, or cationic precursors. High-pressure fluorination techniques also failed to give OF3, ArF, ClF6, and BrF6 salts. New syntheses of SOF4, ClSO2F, and ClOSO2F were developed using ClF as a reactant. Structural investigations of a number of anionic and cationic bromine fluoride complexes were initiated. Data relevant to the synthesis and characterization of ClF3O have been summarized. Author

Descriptors:

• (*OXIDIZERS
• *HALOGENS)
• HIGH TEMPERATURE
• HIGH PRESSURE
• SYNTHESIS(CHEMISTRY)
• IONS
• VIBRATION
• SUBSTRATES
• RAMAN SPECTROSCOPY
• VIBRATION (U) *FLUORIDES
• *LIQUID ROCKET OXIDIZERS
• GLOW DISCHARGES
• FLUORINATION
• BROMINE COMPOUNDS
• ULTRAVIOLET RADIATION
• DISPLACEMENT REACTIONS
• COMPLEX COMPOUNDS
• SULFUR COMPOUNDS
• SINGLE CRYSTALS
• IODINE COMPOUNDS
• ARGON
• ARSENIC COMPOUNDS

Subject Categories:

• Miscellaneous Materials
• Liquid Rocket Propellants

Distribution Statement:

APPROVED FOR PUBLIC RELEASE