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THE PRODUCTION OF PERFLUOROCYCLOPROPANE IN THE REACTION OF OXYGEN ATOMS WITH TETRAFLUOROETHYLENE.
Technical documentary rept.,
AEROSPACE CORP EL SEGUNDO CALIF LAB OPERATIONS
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The reaction of O3P with C2F4 proceeds by the reaction scheme O C2F4 yields CF2O CF2 O C2F4 yields C2F4O 2CF2 yields C2F4 CF2 C2F4 yields cyclo-C3F6 C2F4O C2F4 yields CF2O C-C3F6 C2F4O yields CF2O CF2 where C2F4O is excited intermediate. The ratio k5k11 k5 is 0.15 at 22 C and drops slightly as the temperature is raised. The CF2 radicals produced give the same values for k3k212 as do singlet CF2 radicals produced in another system. Author
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