Accession Number:

AD0478843

Title:

CHEMISTRY OF ALLENIC COMPOUNDS.

Descriptive Note:

Final rept. 1 Jan 62-31 Dec 65,

Corporate Author:

CALIFORNIA UNIV LOS ANGELES DEPT OF CHEMISTRY AND BIOCHEMISTRY

Personal Author(s):

• Jacobs, Thomas L.

Report Date:

1965-12-31

Pagination or Media Count:

19.0

Abstract:

Investigation of the fundamental chemistry of allenic compounds is described, with emphasis on the acetylene-allene rearrangement. Topics covered include Displacement reactions and prototropic rearrangements in four-carbon propargyl and allenyl systems Coupling of 4-chloro -4-methyl -2-pentyne and similar propargyl chlorides with organometallic compounds Allenyl Grignard reagents and Dimerization of allenes. Author

Descriptors:

• *HALOGENATED HYDROCARBONS
• *ALKYNES
• *ALKENES
• HALOGENATED HYDROCARBONS
• EXCHANGE REACTIONS
• DISPLACEMENT REACTIONS
• REACTION KINETICS
• MOLECULAR ASSOCIATION
• CHLORINE COMPOUNDS
• CHEMICAL BONDS
• ORGANOMETALLIC COMPOUNDS
• POLYMERIZATION
• SUBSTITUTION REACTIONS
• GRIGNARD REACTIONS
• STEREOCHEMISTRY
• TWINNING(CRYSTALLOGRAPHY)
• NUCLEAR MAGNETIC RESONANCE
• SPECTROSCOPY
• PHOTOCHEMICAL REACTIONS
• DECOMPOSITION
• DIENES
• MOLECULAR ISOMERISM
• GAS CHROMATOGRAPHY
• INFRARED SPECTRA
• MOLECULAR STRUCTURE

Subject Categories:

• Organic Chemistry
• Atomic and Molecular Physics and Spectroscopy

Distribution Statement:

APPROVED FOR PUBLIC RELEASE