Accession Number:

AD0466967

Title:

RESEARCH ON SYNTHESIS OF UNSATURATED FLUOROCARBON COMPOUNDS

Descriptive Note:

Technical Report,01 Oct 1964,31 Mar 1965

Corporate Author:

FLORIDA UNIV GAINESVILLE GAINESVILLE United States

Personal Author(s):

• Tarrant, Paul
• Perry, Doug
• Tandon, Jai
• Wright, Alan
• Misaki, Susumu

Report Date:

1965-03-31

Pagination or Media Count:

43.0

Abstract:

A study has been made for producing perfluoroallyl bromide and iodide. The latter olefin reacted with alcohols to produce ethers such as CFsub3-CHsub2OCFsub2CFCFsub2. Attempts to prepare CFsub2CFCHsub2CHsub2CHsub2sub2O from the allyl ethers have been carried out but cyclic ethers were formed. An investigation of the radical addition of CFsub3CFsub2CClsub3, CFsub2ClCFsub2-CClsub3, CFClBrCFClBr and CCIsub3CFsub2CFClBr with various olefins has been initiated. Studies of the preparation of perfluoroalkane enoyides have also been initiated.

Descriptors:

• (HALOGENATED HYDROCARBONS
• FLUORINE COMPOUNDS)
• (FLUORINE COMPOUNDS
• HALOGENATED HYDROCARBONS)
• (ALKENES
• FLUORINE COMPOUNDS)
• SYNTHESIS(CHEMISTRY)
• BROMINE COMPOUNDS
• IODINE COMPOUNDS
• ETHERS
• OXYGEN HETEROCYCLIC COMPOUNDS
• LITHIUM COMPOUNDS
• SILANES
• INFRARED SPECTRA
• NUCLEAR MAGNETIC RESONANCE
• CATALYSTS
• ALUMINUM COMPOUNDS
• ZINC
• ELASTOMERS

Subject Categories:

• Organic Chemistry
• Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE