HIGH TEMPERATURE POLAMINE RESINS.
Technical progress rept. no. 1, 15 Mar15 June 64,
QUANTUM INC WALLINGFORD CT
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A literature search was conducted to investigate work done with aromatic amine-organic chloride reactions and organo-sodium amide preparations from amines and amides. Polymers were synthesized from alpha, alpha-dichloro-p-xylylene and diamines of various molecular structures. Polymers with varying characteristics can be made from these materials. Polymers essentially linear in structure but of relative low molecular wt. appeared to be synthesized by the diaminedichloride route. Extensive investigations of polyamine synthesis from sodium salts of amides and amines, and chlorides were conducted. Apparently successful methods were found for preparing sodium derivatives of amides and amines from both solid sodium amide and sodiumammonia solution. Copolymers were prepared from disodium-N,N -diacetyl-pphenylenediamine and N,N -disodium-p-phenylenediamine with alpha, alpha -dichloro--xylene. Author