Accession Number:

AD0431713

Title:

EFFECT OF THE INTERNAL FIELD ON VIRBRATIONAL BAND SHAPES AND INTENSITIES IN LIQUIDS,

Descriptive Note:

Corporate Author:

TUFTS UNIV MEDFORD MASS

Personal Author(s):

Report Date:

1964-01-15

Pagination or Media Count:

20.0

Abstract:

An analysis is given of the effect of the frequency dependence of the internal field upon band shapes and intensities in infrared and Raman spectra of liquids. It is shown that band shape in the Raman case is independent of the form of an isotropic internal field, and therefore a reflection of molecular interaction alone, whereas both effects are operative in generating infrared band shapes. Numerical calculations of infrared band shapes in liquids are presented for the Lorentz and Buckingham internal field functions. Author

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE