POLYMERIZATION OF BIS(2-CHLOROETHYL) VINYLPHOS PHONATE. (polimerizatsiya di-beta, beta'-khlore tilovog-o efira vinilfosfinovoy kisloty)
SCRIPTA TECHNICA INC WASHINGTON DC
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The block polymerization of bis2-chloroethyl vinylphosphonate BCVP in the presence of var ious initiators was investigated. A plot was made of the variation of the initial rate of polymerization with the temperature, and with the concentration of azoisobutyrodinitrile. The total activation energy for the polymerization of BCVP was calculated. The dependence of the polymerization rate of BCVP on the presence of atmospheric oxygen and humidity was demonstrated. The molecular weights of the polymers of BCVP were determined.
- Polymer Chemistry