Accession Number:

AD0395056

Title:

Ionic Fluorine Chemistry.

Descriptive Note:

Semiannual status rept. no. 3, 1 May-30 Nov 68,

Corporate Author:

OLIN MATHIESON CHEMICAL CORP NEW HAVEN CONN CHEMICALS GROUP

Personal Author(s):

Report Date:

1968-12-31

Pagination or Media Count:

20.0

Abstract:

This report describes further attempts to prepare the ClF6- anion. The addition of ClF3 up to 15, HF up to 1, and F2 at F2CsF of 201 to the CsF-ClF5 system did not result in products containing the ClF6- anion. Fluorination of CsClF4 gave only ClF5. No evidence for CsClF6 was found in the solid residues. All evidence gathered to date indicates that CsClF6 does not form in the reaction system CsF-ClF5, or, if it does, it is not stable. An X-ray diffraction pattern of CsClF4 has been obtained and is reported and compared with a pattern previously published by other workers. Author

Subject Categories:

  • Rocket Propellants
  • Solid Rocket Propellants

Distribution Statement:

APPROVED FOR PUBLIC RELEASE