RESEARCH IN HIGH-ENERGY OXIDIZERS.
Final rept. 1 Sep 66-31 Oct 67,
ROCKETDYNE CANOGA PARK CALIF
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The perfluoroformamide-KF system was found to give the complexes KOCFNF22 and KOCNF23. From these a new synthesis of tetrafluorourea evolved. The electrochemical oxidation of KOCF2NF2 to generate N2F4 has been demonstrated, and preliminary polarization data have been obtained. The chemistry of difluoroaminoxy-carbonyl fluoride was studied with respect to its fluorination and condensation reactions. The fluorination of KOCF2NF2 did not give FOCF2NF2 however, with IF7 and N2F4, KOCF2NF2 gave a small amount of NF2OCF2NF2. Iodine heptafluoride did not convert carboxylates to bis-fluoroxy compounds. It was found that K3FCO3 is a double salt and not an addition compound its fluorination did not give CF0F3. A new synthesis of CH3NF2 evolved from CH3CO2O and N2F4 photolysis. Author
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