Accession Number:

AD0377178

Title:

MOLECULAR SUBSTITUTION STUDIES.

Descriptive Note:

Quarterly progress rept. 1 Aug-31 Oct 66,

Corporate Author:

AEROJET-GENERAL CORP AZUSA CALIF

Personal Author(s):

• Hurst,Gerald L.
• Robeson,Ross K.
• Shuey,Harry F.
• Graefe,Allen F.

Report Date:

1966-11-01

Pagination or Media Count:

10.0

Abstract:

It is postulated that changing the chemical environment of unstable NF moieties may yield new energetic materials which have desirable properties. Known high-energy species are being used for the synthesis of NF compounds. Reactions involving the mixture of mercurials obtained from FNClCO2-iPr and Hg with acetyl chloride and with bromine yielded CH3CONFCO2-iPr and FNBrCO2-iPr, respectively. Attempts to prepare iPr-O2CNFNFCO2-iPr, and the cations N2F5 and CNF23 in the form of their SbF6- salts were unsuccessful. Author

Descriptors:

• (*ORGANIC COMPOUNDS
• SUBSTITUTION REACTIONS)
• (*INORGANIC COMPOUNDS
• SUBSTITUTION REACTIONS)
• CHEMICAL COMPOUNDS
• SYNTHESIS(CHEMISTRY)
• CHEMICAL REACTIONS (U) COMPLEX COMPOUNDS
• NITROGEN COMPOUNDS
• FLUORINE COMPOUNDS
• ANTIMONY COMPOUNDS
• FREE RADICALS
• LIQUID ROCKET OXIDIZERS
• IONS
• FLUORIDES
• BROMINE
• ACETIC ACID
• CHLORINE
• ENERGY
• LIQUID ROCKET PROPELLANTS
• MERCURY

Subject Categories:

• Inorganic Chemistry
• Organic Chemistry
• Physical Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE