Accession Number:

AD0368613

Title:

ADVANCED OXIDIZER RESEARCH.

Descriptive Note:

Quarterly progress rept. 1 Jul-30 Sep 65,

Corporate Author:

REACTION MOTORS DIV THIOKOL CHEMICAL CORP DENVILLE N J

Report Date:

1965-09-30

Pagination or Media Count:

72.0

Abstract:

Further experiments on the dehydrofluorination of secondary alkyldifluoramines are described. A new partially dehydrofluorinated product, 1-difluoramino- 2-fluoriminocyclohexane, was obtained by treating bisdifluoramino cyclohexane with basic ion exchange resin for a limited time. Bis difluoramino fluoraminomethoxy pentane was synthesized by the addition of pentanol to perfluoroguanidine. Elemental analyses of the N2F4-AsF5 adduct gave a composition, N2F4AsF5 1.33, indicating a mixture of adducts having 11 and 12 N2F4AsF5 ratios. The structure of the 12 adduct possibly in N2F3As2F11-. The reaction of O2AsF6 with CsClF4 produced O2 and Cl2, as well as CsAsF6, at about 0 C. The reaction of NO2 with AsF5 does not give a molecular adduct NO2.AsF5 as reported in the literature, but rather a mixture of NOAsF6 and NO2AsF6. The presence of ammonium perchlorate as a decomposition product of hydroxylammonium perchlorate was found to be dependent on the removal of oxidizing species from the system and, hence, non-stoichiometric. Author

Subject Categories:

  • Inorganic Chemistry
  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE