RESEARCH IN FLUORO-NITRO COMPOUNDS
Quarterly technical rept. no. 22, 1 Jan-31 Mar 1965.
AEROJET-GENERAL CORP AZUSA CA
Pagination or Media Count:
The reactions of 1-difluoraminobutane and 2-difluoraminobutane with concentrated sulfuric acid gave the monovalent ions, CH2NF-CH2-CH2CH3 and CH3CHNFCH2CH3, respectively. A 11 adduct of isoprene and difluoramine was obtained, using the boron trifluoride complex of phosphoric acid as catalyst. The reaction of 2,2-bisdifluoraminooctane with sulfuric acid, with vigorous agitation, gave 2-octanone. The reaction of alpha, alpha-dibromo-alpha- difluoraminotoluene with sodium 2-propanenitronate gave alphabromo-alpha- fluoriminotoluene. The fluorination of ethyl methoxycarbamate gave N,N- dimethoxyN,N-dicarbethoxyhydrazine instead of the expected NF derivatives. Methyl alpha-difluoraminobutyrate was synthesized, and contrary to the reported difluoraminoacetate, the compound does not undergo dehydrofluorination on storage. An NF-containing compound was obtained in the fluorination of 2,4,6- trichloroaniline.
- Organic Chemistry