Accession Number:

AD0353118

Title:

RESEARCH IN FLUORO-NITRO COMPOUNDS

Descriptive Note:

Quarterly technical summary rept. no. 20, 1 Apr-30 Jun 1964

Corporate Author:

AEROJET-GENERAL CORP AZUSA CA

Report Date:

1964-07-01

Pagination or Media Count:

47.0

Abstract:

The reaction of 1-nitro-1-nitrosocyclohexane with NF2 in the presence of the BF3 complex of H3PO4 gave nitrocyclohexane and 1-nitro-1-fluoroazoxy cyclohexane. The uncatalyzed reaction of alkyl nitrites with NF2 gave the corresponding alcohols. 1-Chloro-1-nitrobutane was nitrosated, and the unstable product was treated with NF2 in fuming H2SO4 to give 1-chloro-1,1-bisNF2 butane. Evidence was obtained showing that N-fluoroformamide is produced in the direct fluorination of formamide.

Subject Categories:

  • Organic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE