Accession Number:

AD0294198

Title:

A NEW SERIES OF ORGANOBORANES. I. THE CHLORI-NATION OF 11,12-DICARBADODECABORANE

Descriptive Note:

Corporate Author:

OLIN MATHIESON CHEMICAL CORP NEW HAVEN CONN

Report Date:

1963-01-02

Pagination or Media Count:

1.0

Abstract:

A detailed investigation of the chlorination of a new series of organoboranes derived from decaborane-14 resulted in the stepwise formation of a number of chlorocarboranes containing from two to eleven chlorine atoms per molecule. Some of their chemical characteristics are described a detailed B11 NMR treatment of the parent carborane B10H10C2H2, B10Cl10C2H2 and B10Cl10C2HCl as related to structural considerations is presented. Author

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE