Accession Number:

AD0292663

Title:

SYNTHESIS OF ORGANOSILICON MONOMERS WITH NITRILE GROUPS

Descriptive Note:

Corporate Author:

FOREIGN TECHNOLOGY DIV WRIGHT-PATTERSON AFB OHIO

Personal Author(s):

Report Date:

1962-10-26

Pagination or Media Count:

1.0

Abstract:

For the purpose of obtaining new organosilicon monomers with nitrile groups, the addition of Cl3SiH to cyclohexene-3-carbonitrile was studied. The best results in the addition of trichlorosilane to cyclohexenecarbonitrile were obtained when tertiary butyl peroxide was used as a catalyst. The use of IR spectra for the identification of the addition products did not give positive results. Considerable amounts up to 60-90 of SiCl4 formed attests to the disproportionation of HSiCl3 under the action of nitrogen-containing compounds present in the reaction mixture. Author

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Distribution Statement:

APPROVED FOR PUBLIC RELEASE