Accession Number:

AD0283582

Title:

INORGANIC HETEROPOLYMERS

Descriptive Note:

Corporate Author:

MICHIGAN STATE UNIV EAST LANSING

Personal Author(s):

Report Date:

1961-09-15

Pagination or Media Count:

1.0

Abstract:

Work continued on the reactions of biscyclopentadienyltit nium dihalides, cp2TiCl2, with sodium organosilanolates and organosilanols. Three new titanium-silicon compounds were prepared. Another titanium compound was isolated as a side product in the reactions of cp2TiCl2 with sodium trimethylsilanolate and sodium dimethylphenylsilanolate, but it has not been fully identified. The stoichiometric study of the reaction of NaOSi03 with 03SnCl, n-C4H92SnCl2 and CH32SnCl2 in benzene has been completed. Since the above reactions were found to be rapid rate processes at room temperature, no detailed reaction mechanisms were established. Products were identified through detailed elemental analysis and infrared spectra. Author

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE