Accession Number:

AD0282177

Title:

PHOSPHINOBORINE POLYMERS

Descriptive Note:

Final rept. Jan-Dec 1961

Corporate Author:

AMERICAN POTASH AND CHEMICAL CORP WHITTIER CA

Personal Author(s):

• Wagner, Rose I.
• Washburn, Robert M.
• Burg, Anton B.

Report Date:

1962-07-01

Pagination or Media Count:

215.0

Abstract:

B-P Polymers A series of new linear poly-P-methyl-n-alkyl-borophanes were prepared and evidence suggests depolymerization of these materials proceeds by loss of monomer units at the chain ends. A number of new P-substituted triborophane derivatives were prepared as well as several partially B- halogenated derivatives of P-hexamethyltriborophane. New Approaches to Thermally Stable Polymers A number of diarylphosphonyl azides, Ar2P0N3, were prepared and characterized. The azides react with trivalent P compounds to yield phosphoranes. Inorganic Polymer Components New IR spectra of R2PBH23 compounds have structural implications bearing upon the theory of their stability. IR spectra also confirm the structure CF3HP0 0H2, relating to the question of the stability of possible polymers having phosphinic-anhydride connections. Trifluormethyl acetoxyphosphines offer a route to P-O-P bonding and to CF3POn polymers.

Descriptors:

• *POLYMERS
• *LAMINATES
• *HEAT RESISTANT PLASTICS
• *PHOSPHINE
• *BORINES
• *PHOSPHORUS COMPOUNDS
• STABILITY
• POLYMERIZATION
• SYNTHESIS(CHEMISTRY)
• CHEMICAL REACTIONS
• MOLECULAR STRUCTURE
• SILICON COMPOUNDS
• PHENYL RADICALS
• ALKYL RADICALS
• DIBORANES
• NITROGEN COMPOUNDS
• AZIDES

Subject Categories:

• Polymer Chemistry
• Plastics

Distribution Statement:

APPROVED FOR PUBLIC RELEASE