Accession Number:

AD0276280

Title:

THERMAL DIFFUSION IN SOLUTIONS OF ELECTROLYTES

Descriptive Note:

Corporate Author:

CAMBRIDGE UNIV (ENGLAND)

Personal Author(s):

Report Date:

1961-12-18

Pagination or Media Count:

1.0

Abstract:

A conductance method has been used for thermal diffusion measurements on 44 aqueous organic and inorganic electrolytes at 25 C, mostly at a concentration of 0.01m. By suitable design of apparatus, measurements at considerably higher concentrations were possible. Departures from predicted behaviour are found to be explicable in terms of inherent systematic errors. Results are quoted as Soret coefficients and heats of transport. A qualitative interpretation of the results is given in the light of current ideas of ion-solvent interactions. Author

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE