Accession Number:

AD0274661

Title:

STUDY LEADING TO THE DEVELOPMENT OF POLYMERS FOR USE IN HIGH TEMPERATURE

Descriptive Note:

Corporate Author:

ILLINOIS UNIV URBANA

Personal Author(s):

Report Date:

1962-02-28

Pagination or Media Count:

1.0

Abstract:

The preparation of trimeric sulfanuric chloride by the thermal decomposition of trichlorophosphazosulfonyl chloride was accomplished. Experiments indicated that the cleavage proceeds in a quantitative way but only two isomeric forms were obtained in low yields. This suggests the possibility that the residue may contain some other isomers, such as the tetramer or higher linear polymers. Attempts to prepare sulfanuric chloride by the reaction of SOCl2 with NH4Cl in symtetrachloroethane as a solvent and in the presence of Cl as an oxidizing agent failed to give positive results. Although the reaction was carried out under different conditions of time and temperature, NH4Cl was recovered always in stoichiometrical quantities. Author

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Distribution Statement:

APPROVED FOR PUBLIC RELEASE