Accession Number:
AD0272855
Title:
STUDY OF SUPEROXIDIZERS
Descriptive Note:
Corporate Author:
OLIN MATHIESON CHEMICAL CORP NEW HAVEN CONN
Personal Author(s):
Report Date:
1961-12-01
Pagination or Media Count:
1.0
Abstract:
Studies were conducted on the preparation and characterization of hydrogen superoxide and superoxidizers such as NF2O2, NF2OONF2, ClF5 and Cl2O8. Electron spin resonance measurements on the H O3 product revealed the presence of a free radical HO2 which disappeared in the temperature range -130 to -120 C. Kinetic studies revealed that t e decomposition of the H O3 product was affected by phase transformations in the frozen matrix. The heat of crystallization of 50 wt H2O2-ice was determined calorimetrically to be 45 calg. The mechanism of peroxide formation from dissociated water vapor was investigated. The reactions of tetrafluorohydrazine with O3, O toms, NO dioxide, NO, Cl2O7 and ClF3 were investigated. Evidence for low temperature N-O-F-containing complexes was found. Author
Descriptors:
- *CHLORINE COMPOUNDS
- *FLUORIDES
- *HYDROGEN COMPOUNDS
- *OXIDES
- *OZONE
- *PEROXIDES
- *ROCKET PROPELLANTS
- OXIDIZERS
- AMIDES
- AMMONIA
- ATOMS
- CHEMICAL REACTIONS
- CHLORIDES
- COMPLEX COMPOUNDS
- DECOMPOSITION
- DISSOCIATION
- HYDROGEN
- INFRARED SPECTROSCOPY
- LIQUEFIED GASES
- CRYOGENICS
- OXIDIZERS
- OXYGEN COMPOUNDS
- REACTION KINETICS
- SPECTROGRAPHY
- SYNTHESIS
- THERMOCHEMISTRY
- WATER VAPOR