Accession Number:

AD0271791

Title:

COCRYSTALLIZATION OF ULTRAMICRO QUANTITIES OF IRON AND OTHER ELEMENTS WITH OXINE GENERATED IN SITU

Descriptive Note:

Corporate Author:

NAVAL RADIOLOGICAL DEFENSE LAB SAN FRANCISCO CA

Personal Author(s):

Report Date:

1961-10-31

Pagination or Media Count:

30.0

Abstract:

The cocrystallization of Fe in trace quantities with oxine formed homogeneously in solution by the hydrolysis of 8-acetoxyquinoline was studied. The distribution of microcomponent between the solid phase and the mother liquor was profoundly affected by the degree of supersaturation. After relief from supersaturation, a constant distribution coefficient was calculated by an equation which was predicated upon the Doerner-Hoskins equilibrium. The cocrystallization of other elements was also examined with an arbitrarily established set of conditions. Pu, Ce, and Pr were quantitatively recovered from solution.

Subject Categories:

  • Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE