COCRYSTALLIZATION OF ULTRAMICRO QUANTITIES OF IRON AND OTHER ELEMENTS WITH OXINE GENERATED IN SITU
NAVAL RADIOLOGICAL DEFENSE LAB SAN FRANCISCO CA
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The cocrystallization of Fe in trace quantities with oxine formed homogeneously in solution by the hydrolysis of 8-acetoxyquinoline was studied. The distribution of microcomponent between the solid phase and the mother liquor was profoundly affected by the degree of supersaturation. After relief from supersaturation, a constant distribution coefficient was calculated by an equation which was predicated upon the Doerner-Hoskins equilibrium. The cocrystallization of other elements was also examined with an arbitrarily established set of conditions. Pu, Ce, and Pr were quantitatively recovered from solution.
- Inorganic Chemistry