Accession Number:

AD0271451

Title:

SYSTEMS CONTAINING A SILICON-OXYGEN-METAL LINKAGE

Descriptive Note:

Corporate Author:

INORGANIC RESEARCH LAB WESTERN RESERVE UNIV CLEVELAND OHIO

Personal Author(s):

• CHAMBERLAIN,M.M.
• JABS,G.A.
• WAYLAND,B.B.

Report Date:

1962-01-31

Pagination or Media Count:

1.0

Abstract:

Methods were developed for the preparation of the vanadium siloxy esters tristriphenylsiloxy vanadate and tristriphenylsiloxy thiovanadate. Modifications of the reported methods to give high yields of tetrakistriphenylsiloxy vanadium are discussed. A quick and accurte method for the quantitative determination of Si and V in these esters was developed.

Descriptors:

• *ORGANOMETALLIC COMPOUNDS
• *SILICONES
• *VANADATES
• CHEMICAL ANALYSIS
• ESTERS
• PHENYL RADICALS
• SYNTHESIS
• ORGANIC SULFUR COMPOUNDS
• VANADIUM COMPOUNDS

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE