Thermochemistry of Oxygen-Fluorine Bonding
Quarterly technical summary report no. 2, 1 Jul-30 Sep 1961
UNITED TECHNOLOGY CENTER SUNNYVALE CA
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The objectives of the study were 1 Modification of existing experimental equipment for a more detailed study of the synthesis of NO2F and NO3F 2 Further development of consistent and accurate analytical techniques including mass spectroscopy, gas chromatography, hydrolysis, purification by fractional distillation, and infrared spectrophotometry for determination of reaction products in the synthesis of NO2F and NO3F 3 Assembly and calibration of a suitable flow calorimeter for measurement of the heats of formation of NO2F, NO3F, and ClO4F 4 Synthesis and purification of NO2F from elemental F and NO2 and NO3F from concentrated HNO3 and elemental F and 5 Preliminary evaluation of the heat of formation of NO2F from measurement of the heat evolved during reaction of elemental F and NO2.
- Organic Chemistry