Accession Number:

AD0259311

Title:

THE ISOTOPIC-EXCHANGE REACTIONS OF B2H6 WITH DT, HT, AND HD

Descriptive Note:

Corporate Author:

JOHNS HOPKINS UNIV BALTIMORE MD

Personal Author(s):

Report Date:

1961-12-01

Pagination or Media Count:

1.0

Abstract:

The isotope effects in the diborane-hydrogen exchange and in the pentaborane-diborane exchange reactions were studied using deuterium and tritium as tracers. In the former reaction an inverse isotope effect was observed, whereas in the latter a normal isotope effect was obtained. The effects are interpreted in terms of previously proposed mechanisms. utho

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Distribution Statement:

APPROVED FOR PUBLIC RELEASE