Accession Number:

AD0258248

Title:

REACTIONS OF AZIRIDINES WITH ALCOHOLS

Descriptive Note:

Corporate Author:

INTERCHEMICAL CORP NEW YORK

Personal Author(s):

• RESNICK,P.
• MEIER,E.A.

Report Date:

1961-05-31

Pagination or Media Count:

1.0

Abstract:

The reaction of 1-p-chlorobenzoyl aziridine in excess EtOH was studied, varying the acid catalysts. A rate study was done at 30 C using varying amounts of H2SO4. The isomer distribution of 2-methyl and 2,2-dimethyl aziri ine and certain of their acylated derivatives was further investigated. Preliminary experiments with N,N1,2-propylene-2,3,5,6-tetrachloroterephthal-AMIDE AND TRIETHYLENEGLYCOL GAVE EVIDENCE OF REACTION UNDER BASE CATALYSIS, AS INDICATED BY MARKED VISCOSITY INCREASES. Author

Descriptors:

• *ALCOHOLS
• *ETHYLENEIMINES
• ACIDS
• AMIDES
• CHEMICAL RADICALS
• CATALYSIS
• CATALYSTS
• CHEMICAL REACTIONS
• CHLORIDES
• ETHANOLS
• ETHYLENES
• GLYCOLS
• HYDROLYSIS
• METHYL RADICALS
• NUCLEAR ISOMERS
• POLYMERS
• PROPENES
• SULFURIC ACID
• SYNTHESIS

Subject Categories:

Distribution Statement:

APPROVED FOR PUBLIC RELEASE