Some Reactions of Peroxydisulfuryl Difluoride
WASHINGTON UNIV SEATTLE DEPT OF CHEMISTRY
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The reactions of peroxydisulfuryl difluoride with several substances have been examined. Three new fluorosulfonates, octafluorobisfluorosulfonato cyclopentane C5F8SO3F2, tetrafluorobisfluorosulfonatoethane C2F4SO3F2 , and tetrafluorobisfluorosulfonatosulfur VI SF4SO3F2 were produced by direct combination of peroxydisulfuryl difluoride with perfluorocyclopentene C5F8 and tetrafluoroethyleneC2F4 at room temperature and with sulfur tetrafluoride SF4 a 128 degrees respectively. These new compounds have been characterized. Structures nave been confirmed by mass, nuclear magnetic resonance and infrared spectra. A white solid, dioxobisfluorosulfonato molybdenum VI MoO2SO3F2, was obtained with either molybdenum hexacarbonyl or molybdenum metal.
- Inorganic Chemistry