Accession Number:

AD0255655

Title:

Some Reactions of Peroxydisulfuryl Difluoride

Descriptive Note:

Technical rept.

Corporate Author:

WASHINGTON UNIV SEATTLE DEPT OF CHEMISTRY

Personal Author(s):

Report Date:

1961-12-01

Pagination or Media Count:

26.0

Abstract:

The reactions of peroxydisulfuryl difluoride with several substances have been examined. Three new fluorosulfonates, octafluorobisfluorosulfonato cyclopentane C5F8SO3F2, tetrafluorobisfluorosulfonatoethane C2F4SO3F2 , and tetrafluorobisfluorosulfonatosulfur VI SF4SO3F2 were produced by direct combination of peroxydisulfuryl difluoride with perfluorocyclopentene C5F8 and tetrafluoroethyleneC2F4 at room temperature and with sulfur tetrafluoride SF4 a 128 degrees respectively. These new compounds have been characterized. Structures nave been confirmed by mass, nuclear magnetic resonance and infrared spectra. A white solid, dioxobisfluorosulfonato molybdenum VI MoO2SO3F2, was obtained with either molybdenum hexacarbonyl or molybdenum metal.

Subject Categories:

  • Inorganic Chemistry

Distribution Statement:

APPROVED FOR PUBLIC RELEASE