Accession Number : ADA600892


Title :   Curing of a Bisphenol-E Based Cyanate Ester using Magnetic Nanoparticles as an Internal Heat Source through Induction Heating


Descriptive Note : Journal article


Corporate Author : AIR FORCE RESEARCH LAB EDWARDS AFB CA ROCKET PROPULSION DIV


Personal Author(s) : Hubbard, Jeremiah W ; Orange, Francois ; Guinel, Maxime J ; Guenthner, Andrew J ; Mabry, Joseph M ; Sahagun, Christopher M ; Rinaldi, Carlos


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/a600892.pdf


Report Date : Nov 2013


Pagination or Media Count : 26


Abstract : We report on the control of cyclotrimerization forming a polycyanurate polymer using magnetic iron oxide nanoparticles in an alternating current (AC) field as an internal heat source, starting from a commercially available monomer. Magnetic nanoparticles were dispersed in the monomer and catalytic system using sonication and the mixture was subjected to an alternating magnetic field, causing the magnetic nanoparticles to dissipate the energy of the magnetic field in the form of heat. Internal heating of the particle/monomer/catalyst system was sufficient to start and sustain the polymerization reaction, producing a cyanate ester network with conversion that compared favorably to polymerization through heating in a conventional laboratory oven. The two heating methods gave similar differential scanning calorimetry temperature profiles, conversion rates, and glass transition temperatures when using the same temperature profile. The ability of magnetic nanoparticles in an AC field to drive the curing reaction should allow for other reactions forming high-temperature thermosetting polymers and for innovative ways to process such polymers.


Descriptors :   *CURING , *CYANATES , ALTERNATING CURRENT , INDUCTION HEATING , IRON OXIDES , MAGNETIC FIELDS , MAGNETIC MATERIALS , NANOPARTICLES , POLYMERIZATION


Subject Categories : Polymer Chemistry


Distribution Statement : APPROVED FOR PUBLIC RELEASE