Accession Number : ADA266710


Title :   Syntheses of 2,9-Bis(halomethyl)-1,10-phenanthroline: Potential Robust Ligands for Metal Oxidation Catalysts


Corporate Author : FLORIDA UNIV GAINESVILLE DEPT OF CHEMISTRY


Personal Author(s) : Beer, Robert H ; Jimenez, Jose ; Drago, Russell S


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/a266710.pdf


Report Date : Jan 1993


Pagination or Media Count : 3


Abstract : Free radical halogenation of 2,9-dimethyl-1,10-phenanthroline with N- bromosuccinimide and N-chlorosuccinimide form the known alpha methyl derivatives 2,9-bis(trihalomethyl)-1,10-phenanthroline can be used for one-step syntheses of oxidatively resistant fluoro- and partially reduced chloromethyl derivatives capable of coordination to metal oxidation catalysts. (Author)


Descriptors :   *METHYL RADICALS , *HYDROCARBONS , *LIGANDS , *CATALYSTS , *HALOGENS , *RUTHENIUM , METALS , SYNTHESIS , CHLORINE , SUCCINIMIDES , BROMINE , FREE RADICALS , OXYGEN , FLUORINE , OXIDATION , NITROGEN , REPRINTS


Subject Categories : Inorganic Chemistry
      Organic Chemistry
      Physical Chemistry


Distribution Statement : APPROVED FOR PUBLIC RELEASE