Accession Number : ADA263085
Title : Analytical Applications of Electrified Interfaces Between Two Immiscible Solutions
Descriptive Note : Technical rept.
Corporate Author : NORTHERN ILLINOIS UNIV DE KALB DEPT OF CHEMISTRY
Personal Author(s) : Vanysek, Petr
Report Date : 07 Apr 1993
Pagination or Media Count : 26
Abstract : Interfaces between two immiscible electrolyte solutions have some properties that can be investigated and utilized by methods of electrochemistry. This review compares electrochemistry on such interfaces with electrochemistry of metal electrodes immersed in solutions. It builds on knowledge of methods of electroanalysis and shows how it can be applied to the interfaces of immiscible liquids. A simple differential adapter that can convert any potentiostat to the 4-electrode potentiostate needed for the work is described. Experimental techniques involving potentiometry, polarography with dropping electrode, voltammetry and microinterfaces are outlined.... Electrochemistry on immiscible interfaces, Review, Charge transfer, Microinterfaces, Electroanalytical chemistry.
Descriptors : *ELECTROCHEMISTRY , *POTENTIOSTATIC TECHNIQUES , *ANALYTICAL CHEMISTRY , METALS , INTERFACES , ELECTROLYTES , POLAROGRAPHY , POTENTIOMETRIC ANALYSIS , VOLTAMMETRY , CHARGE TRANSFER , ELECTRODES , LIQUIDS
Subject Categories : Physical Chemistry
Distribution Statement : APPROVED FOR PUBLIC RELEASE