Accession Number : ADA263085


Title :   Analytical Applications of Electrified Interfaces Between Two Immiscible Solutions


Descriptive Note : Technical rept.


Corporate Author : NORTHERN ILLINOIS UNIV DE KALB DEPT OF CHEMISTRY


Personal Author(s) : Vanysek, Petr


Full Text : https://apps.dtic.mil/dtic/tr/fulltext/u2/a263085.pdf


Report Date : 07 Apr 1993


Pagination or Media Count : 26


Abstract : Interfaces between two immiscible electrolyte solutions have some properties that can be investigated and utilized by methods of electrochemistry. This review compares electrochemistry on such interfaces with electrochemistry of metal electrodes immersed in solutions. It builds on knowledge of methods of electroanalysis and shows how it can be applied to the interfaces of immiscible liquids. A simple differential adapter that can convert any potentiostat to the 4-electrode potentiostate needed for the work is described. Experimental techniques involving potentiometry, polarography with dropping electrode, voltammetry and microinterfaces are outlined.... Electrochemistry on immiscible interfaces, Review, Charge transfer, Microinterfaces, Electroanalytical chemistry.


Descriptors :   *ELECTROCHEMISTRY , *POTENTIOSTATIC TECHNIQUES , *ANALYTICAL CHEMISTRY , METALS , INTERFACES , ELECTROLYTES , POLAROGRAPHY , POTENTIOMETRIC ANALYSIS , VOLTAMMETRY , CHARGE TRANSFER , ELECTRODES , LIQUIDS


Subject Categories : Physical Chemistry


Distribution Statement : APPROVED FOR PUBLIC RELEASE